Chemical thermodynamics Topics - IIT JEE Syllabus

1

The second law of thermodynamics

2m1/10

📌 Key FormulaSpontaneous processes, entropy increase.

2

Fundamentals of thermodynamics

2m1/10

📌 Key FormulaSystem, surroundings, state functions.

3

System and surroundings

2m1/10

📌 Key FormulaOpen, closed, isolated.

4

Extensive and intensive properties

2m1/10

📌 Key FormulaDepend on amount vs independent.

5

State functions

2m1/10

📌 Key FormulaPath independent, e.g., U, H, G.

6

Types of processes

2m1/10

📌 Key FormulaIsothermal, adiabatic, isobaric, isochoric.

7

The first law of thermodynamics- Concept of work

2m2/10

📌 Key FormulaΔU = q + w (sign convention)

8

Heat internal energy and enthalpy

2m2/10

📌 Key FormulaH = U + PV, ΔH = q_p

9

Heat capacity and molar heat capacity

2m2/10

📌 Key FormulaC = q/ΔT, C_p - C_v = R for ideal gas.

10

Hess’s law of constant heat summation

2m3/10

📌 Key FormulaΔH_reaction = Σ ΔH_products - Σ ΔH_reactants

11

Enthalpies of bond dissociation, combustion, formation

2m2/10

📌 Key FormulaDefinitions and calculations.

12

Enthalpies of atomization, sublimation, phase transition,

2m1/10

📌 Key FormulaDefinitions.

13

Enthalpies of hydration, ionization, and solution

2m1/10

📌 Key FormulaDefinitions.

14

Spontaneity of processes

2m2/10

📌 Key FormulaΔS_universe > 0, ΔG < 0

15

S of the universe and G of the system as criteria for spontaneity

2m2/10

📌 Key FormulaΔG = ΔH - TΔS

16

G (Standard Gibbs energy change) and equilibrium constant

2m3/10

📌 Key FormulaΔG° = -RT ln K