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  1. Exams
  2. IIT JEE
  3. Chemistry
  4. Solutions
48 marks

Solutions

This chapter deals with different types of solutions, their concentrations, and colligative properties.

16 Topics
35h prep
2.7% subject weight
16 Topics
1

Vapour pressure

2m1/10
πŸ“Œ Key FormulaOf pure components and mixtures.
2

Introduction of solutions

2m1/10
πŸ“Œ Key FormulaHomogeneous mixture.
3

Molality

2m2/10
πŸ“Œ Key Formulam = moles of solute / kg of solvent
4

Molarity

2m2/10
πŸ“Œ Key FormulaM = moles of solute / L of solution
5

Mole fraction

2m2/10
πŸ“Œ Key Formulax_A = n_A / Ξ£ nα΅’
6

Percentage (by volume and mass both)

2m2/10
πŸ“Œ Key Formulaw/w%, v/v%, w/v%
7

The vapour pressure of solutions

2m1/10
πŸ“Œ Key FormulaVaries with composition.
8

Raoult's Law

2m2/10
πŸ“Œ Key FormulaP_A = x_A P_AΒ°
9

Ideal and non-ideal solutions

2m1/10
πŸ“Œ Key FormulaRaoult's law obeyed or not.
10

Composition

2m2/10
πŸ“Œ Key FormulaOf liquid and vapor phases.
11

Plots for ideal and non-ideal solutions

2m2/10
πŸ“Œ Key FormulaVapor pressure vs mole fraction.
12

Colligative properties of dilute solutions

- A relative lowering of vapour pressure. - depression of freezing point - The elevation of boiling point - Osmotic pressure;

2m3/10
πŸ“Œ Key FormulaΞ”P = PΒ° x_B, Ξ”T_f = K_f m, Ξ”T_b = K_b m, Ο€ = CRT
13

Determination of molecular mass using colligative properties

2m3/10
πŸ“Œ Key FormulaFrom formulas above.
14

Abnormal value of molar mass

2m3/10
πŸ“Œ Key FormulaDue to association or dissociation, van't Hoff factor i.
15

Van’t Hoff factor and its significance

2m3/10
πŸ“Œ Key Formulai = actual number of particles / formula units, colligative property ∝ i
16

Normality

2m2/10
πŸ“Œ Key FormulaN = n Γ— M, where n is n-factor.